Article de journal
Pulse irradiation of aqueous solutions containing ferrous and chloride ions

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Détails sur la publication
Sous-titre: Reaction between Cl2- and HO2
Liste des auteurs: C. W. Gilbert, R. B. Ingalls and A. J. Swallow
Editeur: Elsevier
Année de publication: 1977
Journal: Radiation Physics and Chemistry
Nom du journal dans la source: RADIATION PHYSICS AND CHEMISTRY
Numéro du volume: 10
Numéro de publication: 4
Page d'accueil: 221
Dernière page: 225
Nombre de pages: 5
ISSN: 0969-806X
Web of Science ID: A1977EC13800001
Scopus ID: 1642457665

Measurements have been made of the reduced yields of ferric ions which are obtained when pulses of fast electrons are used to irradiate air-saturated solutions of ferrous ions containing various concentrations of chloride ions. The yields for solutions containing up to 10-2 mol dm-3chloride cannot be explained by interaction between H and Cl or Cl2- but can be quantitatively accounted for if the reaction,

Cl2-+HO2→2Cl-+H++O2" role="presentation" style="display: inline-block; line-height: normal; font-size: 16.2px; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border-width: 0px; border-style: initial; position: relative;">Cl2-+HO2→2Cl-+H++O2

takes place with a rate constant of (4.5±0.5) × 109dm3mol-1 s-1.

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Dernière mise à jour le 2019-31-03 à 10:51